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YVO4 Crystals

YVO4 Crystals

YVO4 Crystals

Yttrium Vanadate(YVO4)

Yttrium Vanadate(YVO4) is a positive uniaxial crystal grown with Czochralski method. It has good temperature stability and physical and mechanical properties. It is ideal for optical polarizing components because of its wide transparency range and large birefringence. It is an excellent synthetic substitute for Calcite (CaCO3) and Rutile (TiO2) crystals in many applications including fiber optic isolators and circulators, interleavers, beam displacers and other polarizing optics ( refer to Table 1).

Table 1.Comparison of basic properties between YVO4 and Other Birefringent Crystals.

 
YVO4
TiO2
CaCO3
LiNbO3
Thermal Expansion (/℃)
c-axis
11.4x10-6
9.2x10-6
26.3x10-6
16.7x10-6
a-axis
4.4x10-6
7.1x10-6
5.4x10-6
7x10-6
Refractive Index
no
1.9447@1550nm
2.454@1530nm
1.6346@1497nm
2.2151@1440nm
ne
2.1486@1550nm
2.710@1530nm
1.4774@1497nm
2.1413@1440nm
Birefringence(ne-no)
0.2039@1550nm
0.256@1530nm
-0.1572@1497nm
-0.0738@1440nm
Mohs Hardness
5
6.5
3
5
Deliquescence
None
None
Weak
None
Transparency range
0.4-5μm
0.4-5μm
0.35-2.3μm
0.4-5μm

Basic Properties of YVO4 crystal
Transparency Range:
High transmittance from 0.4 to 5 μm
Crystal Symmetry:
Zircon Tetragonal, space group D4h
crystal Cell:
a=b=7.12A;c=6.29A
Density:
4.22 g/cm3
Mohs Hardness:
5, glass-like
Hygroscopic Susceptibility:
Non-hygroscopic
Thermal Expansion Coefficiet:
αa=4.43x10-6/K;αc=11.37x10-6/K
Thermal Conductivity Coefficient:
//C:5.23 W/m/K;⊥C:5.10 W/m/K
Crystal Class:
Positive uniaxial with no=na=nb,ne=nc
Thermal Optical Coefficient:
Dna/dT=8.5x10-6/K;dnc/dT=3.0x10-6/K
Refractive Indices, Birefringence (△n=ne-no) and Walk-off Angle at 45°(ρ):
no=1.9929,ne=2.2154,△n=0.2225,ρ=6.04° at 630nm
no=1.9500,ne=2.1554,△n=0.2054,ρ=5.72° at 1300nm
no=1.9447,ne=2.1486,△n=0.2039,ρ=5.69° at 1550nm
Sellmeier Equation (λ in μm):
no2=3.77834+0.069736/(λ2-0.04724)-0.0108133λ2 ne2=4.59905+0.110534/(λ2-0.04813)-0.0122676λ2
YVO4 crystal application
YVO4 crystal are widely used in fiber-optic isolators,beam displacers for fiber optical circulators, and interleavers, etc.
 

1.Specifications of birefringent wedges for fiber-optic isolators

 
Aperture
1.0x 1.0mm2 to 4x4mm2
Dimension tolerance
+/-0.05mm
Wedge Angle tolerance
+/-0.1°
Optical axis orientation
+/-0.5°
Flatness
λ/4 @ 632.8 nm
Surface Quality
20-10
AR-coating
R<0.2% @1550 or 1310nm
Standard Size
1.25mmx1.25mmx0.5mm with 13° or 15° wedge, phi=22.5°
 
 

Specifications of YVO4 beam displacers for fiber-optic circulators or interleaver

Dimension tolerance
W(+/-0.05mm)xH(+/-0.05mm)xL(+/-0.1mm)
Optical axis orientation
+/-0.5°
Parallelism
<15 arc sec
Perpendicularity
<10 arc min
Flatness
λ/4 @ 632.8nm
Surface Quality
20/10
AR-coating
R<0.2% @1550 or 1310nm +/-40nm
Standard Size
Note:Other sizes and specifications are available upon request
2.6x2.6x10mm, θ=45°,Φ=0°

 

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